Metallurgical Abstracts on Light Metals and Alloys vol. 58
Corrosion Study of Aluminum 7075 Alloy in Cationic Aqueous Medium by Surface Analysis
Md. Saiful Islam*,**, Masatoshi Sakairi***, Akira Kaneko**** and Md. Shakhawat Hossain*****
* Department of Applied Chemistry and Chemical Engineering, University of Rajshahi
** Graduate School of Engineering, Hokkaido University
*** Faculty of Engineering, Hokkaido University
**** Nikkei Research & Development Center, Nippon Light Metal Co. Ltd.
***** Bangladesh Sericulture Research and Training Institute
[Published in Materials Transactions, Vol. 65 (2024), pp. 389-397]
https://doi.org/10.2320/matertrans.MT-C2023009
E-mail: msakairi[at]eng.hokudai.ac.jp
Key Words: aluminum alloy, oxide films, corrosion, SEM, EDS, XPS
The results of the corrosion nature of aluminum 7075 alloy in a cation-containing aqueous medium are reported by using gravimetric tests and surface analysis. The investigation showed a substantial increase in the mass of the specimens after the immersion experiments, while a minor mass change was seen in the zinc ions containing solution. Energy dispersive spectroscopic mapping and cross-sectional pictures showed that the specimen submerged in the zinc ions containing solution developed a zinc-linked layer. The results of X-ray photoelectron spectroscopy showed that aluminum hydroxide was deposited on the surface, and a tiny amount was deposited on the specimen that was sunk in the solution containing zinc ions. The present study suggests that the zinc-related layer prevents the alloy from corroding.
Corrosion mechanism of aluminum 7075 alloy in aqueous medium with (a) sodium ions and magnesium ions, and (b) zinc ions at 25°C.