Achieving high‑T_c superconductivity in Magnéli phase based on Ti oxides: prediction by machine learning and material synthesis by high‑pressure torsion processing

We explored superconductors with high superconducting transition temperatures (T_c) tuning the stability of Magnéli phase through high-pressure torsion (HPT). We successfully found superconducting states with T_c = 4.0 and 7.3 K for a composition of Al:Ti = 1:2 in the mixture of Al and surface-oxidized Ti powders. Another magnetic anomaly was also observed at ~ 93 K, being supported by the T_c prediction using the machine learning for the Al–Ti–O system. In this study, the HPT processing was also performed on a Magnéli material Ti₄O₇ and such mixtures of stable materials as Al + TiO₂, Al₂O₃ + Ti, Al₂O₃ + TiO₂, and Al + Ti₄O₇. In HPT processed Ti₄O₇, the metal–insulator transition was maintained even after the HPT processing. HPT experiments using stable oxides indicate the difficulty of newly stabilizing the Magnéli phase starting from thermodynamically stable materials under severe plastic deformation. A series of attempts reveals that the superconducting state in the mixture with ratio Al:Ti = 1:2 is attributed to both strained Ti-oxide created on the surface of the Ti powder and its reaction with Al under HPT processing, resulting in the stabilization of a Magnéli phase.